Please fill out the fields below so we can help you better. Note: you must provide your domain name to get help. Domain names for issued certificates are all made public in Certificate Transparency logs (e.g. crt.sh | example.com), so withholding your domain name here does not increase secrecy, but only makes it harder for us to provide help.
$ nmap -Pn -p80,443 21cellars.com
Starting Nmap 7.80 ( https://nmap.org ) at 2023-07-10 15:04 PDT
Nmap scan report for 21cellars.com (71.212.163.125)
Host is up (0.016s latency).
rDNS record for 71.212.163.125: 71-212-163-125.tukw.qwest.net
PORT STATE SERVICE
80/tcp closed http
443/tcp closed https
Nmap done: 1 IP address (1 host up) scanned in 0.41 seconds
I have both ports open on my router. When I run nmap with my domain multiple times the status alternates between "closed" and "filtered" on both ports. Also, when I try to create the certificate from the Synology Diskstation page sometimes it says it cannot access because the port is closed and sometimes it gets through and says "Maximal certificate requests reached for this domain name." When the later occurs does that mean I am getting through to Let's Encrypt (through the appropriate ports) and just getting denied because I have made too many attempts? If so, when does it reset so I can try again?
You might have an active firewall that is blocking (filtering) requests. Check your router and other equipment settings.
This is a confusing message. Let's Encrypt does have limits but this is not the exact error message from Let's Encrypt when you reach LE limits. When I have seen this error in this forum it is usually something wrong with the Synology device. You could search this forum or try a Synology support forum. It's a good chance whatever is causing your "closed" and "filtering" is the root cause of this error.
Using the public logs (below), I don't see that you are affected by Let's Encrypt limits (link here). With your custom domain the most likely would be the limit on 5 certs per week with the identical set of domain names. In the current public log I don't see any certs issued in past week. Although the logs sometimes lag by as much as 24 hours.