How could I change Root Directory with command

I try to use "p.StartInfo.WorkingDirectory", seems it's what I need, but after that I faced with error that I wasn't faced before because I'm using "ACMEv2":

Account creation on ACMEv1 is disabled. Please upgrade your ACME client to a version that supports ACMEv2 / RFC 8555. See End of Life Plan for ACMEv1 for details.