Run certbot showing ValueError: ('Expected version spec in'

I am guessing that somebody ran pip install requests on this system, and it's taking precedence over the python2-requests package, which is breaking Certbot.

FWIW we recommend using the Certbot snap to avoid these kinds of issues.

I am guessing that you are going to need to do something like:

sudo pip uninstall requests urllib3
sudo yum -y reinstall python-chardet python-requests python-urllib3

but be forewarned, I do not know if this is going to break other things on your system.