SSL Error when i hit certbot --apache

It doesn't make much sense to me that your OpenSSL command would return a chain up to DST Root CA X3, as acme-v02.api.letsencrypt.org does not send the cross-signed ISRG Root CA X1 intermediate, but just the R3 intermediate.

Maybe your system has the cross-signed ISRG Root X1 certificate stored somewhere?