After just reading the topic title: this is also possible withoutmod_md. It’s possible since a long time, really. Just use SSLCertificateFile and SSLCertificateKeyFiletwice in your Apache HTTPS virtualhost: one set of both for the RSA cert, one set for the ECDSA cert.
But of course it’s great to see mod_md implementing this too!
I adapted the title to make the message more clear. mod_md can now obtain and renew several certificates for the same domain. The use case for this is to equip servers with RSA+ECDSA certificates from Let’s Encrypt.