Does it support Windows Xp users?

SSLv3's problems have nothing to do with Heartbleed.

You may find older posts stating LE certificates are incompatible with Windows XP. This used to be true, but was resolved when the default intermediate certificate was changed from Let's Encrypt Authority X1 to Let's Encrypt Authority X3. The reason for that were incompatible extensions that restricted LE from issuing certificates for the .mil TLD.