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Hello,
I've used Let's Encrypt to general a SSL certificate for my webserver hosted on Asustor. But when my domain is accessed from another country(tested using VPN) or from a different network, chrome is saying ERR_SSL_VERSION_OR_CIPHER_MISMATCH.
I'm not sure about how it manages certificates. I installed let's encrypt for generating the certificate though. It uses IPv4. I haven't enabled IPv6 yet.